carbon-based ink characterised by the presence of trace amounts of copper

Egypt
7th Century
Source: Sowmeya Sathiyamani, Mathieu Tillier, Naïm Vanthieghem, Claudia Colini. "Leafing through time: Ink Analysis of the longest Qur’ān on Papyrus", 2023 IMEKO TC-4 International Conference on Metrology for Archaeology and Cultural Heritage, pp. 851-855.
Recipe Details

Ingredients

soot, charcoal, water-soluble binder, gum Arabic, trace copper

Preparation Steps

The carbon ink used in this period is traditionally composed of soot or charcoal mixed with a water-soluble binder, commonly gum Arabic, which is then dispersed in water (p. 851, Section I). The specific ink of this manuscript contains trace amounts of copper which are likely not an intentional ingredient but rather a result of accidental contamination. Possible sources cited include the use of a copper or bronze inkwell during the writing process or copper ions present in the water used to prepare the ink (p. 854, Section V).

Original Recipe Text

The carbon ink used in this period is traditionally composed of soot or charcoal mixed with a water-soluble binder, commonly gum Arabic, which is then dispersed in water (p. 851, Section I). The specific ink of this manuscript contains trace amounts of copper which are likely not an intentional ingredient but rather a result of accidental contamination. Possible sources cited include the use of a copper or bronze inkwell during the writing process or copper ions present in the water used to prepare the ink (p. 854, Section V).

Evidence

"The results indicate that the text was written with a carbon-based ink characterised by the presence of trace amounts of copper, possibly due to impurities in the water or the use of a copper or bronze inkwell. The diacritical dots completing the text were penned using the same ink"

Remarks

The study analyzed three bifolia (68.1, 6, and 7) of the longest extant Qur'an excerpt on papyrus. Raman spectroscopy (532 nm laser) confirmed the use of carbon-based black ink by identifying characteristic D and G bands (p. 853, Fig 3). XRF spatial scans revealed that the copper impurities were present in both the main text and the diacritical dots, suggesting they were penned at the same stage with the same ink (p. 853, Section IV). The use of carbon ink on papyrus is noted as unusual for early Qur'anic fragments, which are more typically found on parchment with iron-gall ink (p. 854, Section V).

Scientific Analysis
Chemical CompositionC (Carbon) with trace Cu (Copper)
Analytical Techniques
digital microscope
XRF
Raman
ultraviolet (395 nm)
visible (white) light source
near infrared (940 nm)
Certainty Level
Confirmed
Instrumentally Verified
Verified
Metadata
Material Type
ink
BinderAcacia gum
ColorBlack
RegionEgypt
Approx. Year650
Source Information
AuthorSowmeya Sathiyamani, Mathieu Tillier, Naïm Vanthieghem, Claudia Colini. "Leafing through time: Ink Analysis of the longest Qur’ān on Papyrus", 2023 IMEKO TC-4 International Conference on Metrology for Archaeology and Cultural Heritage, pp. 851-855.
CollectionP. Hamb. Arab. 68.1, 6 and 7 (Hamburg)
Language
N/A
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