Safranin; mono azo dyes (Ponceau RR, Fast red AV, Crocein Orange, Orange II)
Morocco
19th Century
Source: Amélie Couvrat Desvergnes & Ina Vanden Berghe (2017): Dyestuff Identification and Significance of Interleaves from Moroccan Manuscripts of Dalā’il al-Khayrāt, Studies in Conservation, DOI: 10.1080/00393630.2017.1314585
Recipe Details
Ingredients
aniline oil, tannin, antimony, iron salts, alum
Preparation Steps
Synthetic dyes were applied to paper using various methods often adopted from textile practices. Safranine (Basic Red 2) was often applied in a two-step procedure: first, a substantive dye (like an acid dye) was applied, followed by a second dyeing with the basic dye to produce specific shades with better fastness (p. 10). For cotton and paper dyeing, various mordants such as tannin, antimony, iron salts, and alum were used to obtain specific shades (p. 9). Commercial preparations like Safranine S or Safranine MN were used for bluish or yellowish fuchsia tones respectively (p. 9).
Original Recipe Text
Synthetic dyes were applied to paper using various methods often adopted from textile practices. Safranine (Basic Red 2) was often applied in a two-step procedure: first, a substantive dye (like an acid dye) was applied, followed by a second dyeing with the basic dye to produce specific shades with better fastness (p. 10). For cotton and paper dyeing, various mordants such as tannin, antimony, iron salts, and alum were used to obtain specific shades (p. 9). Commercial preparations like Safranine S or Safranine MN were used for bluish or yellowish fuchsia tones respectively (p. 9).
Evidence
"the analyzed papers of the corpus, both natural and synthetic dyestuffs are encountered. The detection of synthetic dyestuff(s) is a clear evidence useable for a post quem dating of the interleaves in question."
Remarks
Safranin was invented in 1859, and mono azo dyes were developed from 1876 onwards (p. 11). These dyes arrived in big Moroccan cities like Marrakesh, Rabat, and Fes before spreading to remote areas (p. 11). They are vivid but very unstable and sensitive to water, alkali, and alcohol (p. 11).
Scientific Analysis
Chemical CompositionC20H19ClN4 (Safranine T)
Analytical Techniques
strong acidic extract (HCl)
soft acidic extract (OA)
high-performance liquid chromatography with photo diode array detection (RP-HPLC-DAD)
Certainty Level
Confirmed
Instrumentally Verified
Verified
Metadata
Material Type
pigment
ColorOrange
RegionMorocco
Approx. Year1850
Source Information
AuthorAmélie Couvrat Desvergnes & Ina Vanden Berghe
CollectionMorocco
Language
N/A
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