lac dye
Portugal
12th Century
Source: Rita Castro, Adelaide Miranda and Maria João Melo. Interpreting lac dye in medieval written sources: new knowledge from the reconstruction of recipes relating to illuminations in Portuguese manuscripts. ATSR, 2015.
Recipe Details
Ingredients
sticklac, lead white, vermilion, gypsum, calcium carbonate
Preparation Steps
Pink colours were obtained by admixing lac with lead white or with lead white and vermilion (p. 90). In the Alcobaça scriptorium, lac was frequently mixed with gypsum in significant proportions as a filler to create opaque paints (p. 90). Dark reds were obtained by admixing lac with vermilion, a practice characteristic of Santa Cruz manuscripts (p. 90). To achieve a glassy appearance, paints were formulated without fillers but with the help of proteinaceous binders like parchment glue and/or egg white (p. 90). The incorporation of resin components via heating above 60°C or using basic extraction solutions (pH > 8) promotes the dissolution of shellac constituents into the final paint (p. 94).
Original Recipe Text
Pink colours were obtained by admixing lac with lead white or with lead white and vermilion (p. 90). In the Alcobaça scriptorium, lac was frequently mixed with gypsum in significant proportions as a filler to create opaque paints (p. 90). Dark reds were obtained by admixing lac with vermilion, a practice characteristic of Santa Cruz manuscripts (p. 90). To achieve a glassy appearance, paints were formulated without fillers but with the help of proteinaceous binders like parchment glue and/or egg white (p. 90). The incorporation of resin components via heating above 60°C or using basic extraction solutions (pH > 8) promotes the dissolution of shellac constituents into the final paint (p. 94).
Evidence
"In a previous study, analytical techniques identified lac dye in dark reds from Portuguese illuminations by comparison with historical reproductions (Castro et al. 2014). Lac dye was produced mainly in southern and southeastern Asia... its main components are laccaic acids A and B; laccaic acids C, D and E also found in minor quantities... also contains erythrolaccin, which is responsible for the yellowish-orange hue that characterises the resin."
Remarks
In the Alcobaça scriptorium, gypsum was found in significant proportions as a filler, whereas in Santa Cruz and Lorvão, calcium carbonate was more prevalent (p. 90). The research highlights that lac dye confirmed the existence of an Arabic and Jewish trade network in Portugal during the Romanesque period (p. 90). Analytical results from microfluorimetry display two bands with maxima at 526 and 562 nm, typical for lac reproductions with alum (p. 94).
Scientific Analysis
Chemical Compositionlaccaic acids A, B, C, D, E and erythrolaccin
Analytical Techniques
infrared (IR) spectroscopy
UV-Vis
Raman
microfluorimetry
high performance liquid chromatography (HPLC)
fibre optic reflectance spectroscopy (FORS)
Certainty Level
Confirmed
Instrumentally Verified
Verified
Metadata
Material Type
pigment
BinderCollagen glue
ColorRed
RegionPortugal
Approx. Year1150
Source Information
AuthorRita Castro, Adelaide Miranda and Maria João Melo. Interpreting lac dye in medieval written sources: new knowledge from the reconstruction of recipes relating to illuminations in Portuguese manuscripts. ATSR, 2015.
CollectionSão Mamede of Lorvão, Santa Cruz of Coimbra and Santa Maria of Alcobaça monasteries
Language
N/A
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