chrome logwood (Cr-logwood) ink

Slovenia
19th Century
Source: Retko, K., Legan, L., Kosel, J. et al. Identification of iron gall inks, logwood inks, and their mixtures using Raman spectroscopy, supplemented by reflection and transmission infrared spectroscopy. Herit Sci 12, 212 (2024).
Recipe Details

Ingredients

potassium chromate, natural logwood extract, ultrapure water

Preparation Steps

As per (p. 4), 0.005 g of potassium chromate dissolved in 50 mL water, 1 g logwood extract added, and the solution heated for 30 minutes. This formulation is noted for not requiring a separate binder (p. 2).

Original Recipe Text

As per (p. 4), 0.005 g of potassium chromate dissolved in 50 mL water, 1 g logwood extract added, and the solution heated for 30 minutes. This formulation is noted for not requiring a separate binder (p. 2).

Evidence

"To prepare chrome logwood (Cr-logwood) ink, 0.005 g of potassium chromate were dissolved in 50 mL of ultrapure water, 1 g of logwood extract was added, and the solution was heated for about 30 min."

Remarks

Introduced in the 19th century as a non-corrosive alternative to iron gall ink to protect metal nibs (p. 3). Analysis with a 785 nm line exhibited a low signal-to-noise ratio, but 532 nm excitation clearly showed hematein-related features (p. 12, 13). Transmission FTIR of Cr-logwood ink powder shows a strong band at ca. 1140 cm−1 assigned to residual potassium chromate (p. 13).

Scientific Analysis
Chemical Compositionhematein-chromium complex
Analytical Techniques
Raman
FTIR
Certainty Level
Confirmed
Instrumentally Verified
Verified
Metadata
Material Type
ink
Paper TypeWhatman™ paper No. 1
ColorBlack
RegionSlovenia
Approx. Year1850
Source Information
AuthorRetko, K., Legan, L., Kosel, J. et al. Identification of iron gall inks, logwood inks, and their mixtures using Raman spectroscopy, supplemented by reflection and transmission infrared spectroscopy. Herit Sci 12, 212
CollectionResearch Institute, Institute for the Protection of Cultural Heritage of Slovenia
Language
N/A
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