graphite particles

Egypt
16th Century
Source: Hassan, R. R. A., Ali, M. F., Fahmy, A. A., Ali, H. M., & Salem, M. Z. (2020). Documentation and Evaluation of an Ancient Paper Manuscript with Leather Binding Using Spectrometric Methods. Journal of Chemistry, 2020, 1-10.
Recipe Details

Ingredients

graphite particles

Preparation Steps

The ink used in the manuscript is a carbon-based ink (p. 2). Laboratory testing using a 5% solution of iron and potassium cyanide with 1% hydrochloric acid confirmed the absence of iron-gall components (p. 5). Subsequent X-ray diffraction of the ink residues confirmed the ink is composed of graphite particles, visible as a distinct peak in the diffractogram (p. 5, 7).

Original Recipe Text

The ink used in the manuscript is a carbon-based ink (p. 2). Laboratory testing using a 5% solution of iron and potassium cyanide with 1% hydrochloric acid confirmed the absence of iron-gall components (p. 5). Subsequent X-ray diffraction of the ink residues confirmed the ink is composed of graphite particles, visible as a distinct peak in the diffractogram (p. 5, 7).

Evidence

"A preliminary chemical test was undertaken to identify the ink type... which proves to be carbon ink. A fraction of the paper containing ink residues was analyzed using X-ray diffraction and showed that the carbon ink is composed of graphite particles (Figure 6)."

Remarks

The graphite-based carbon ink is noted for its stability, as it does not fade over time when exposed to light or chemicals (p. 7). However, the researchers note that such ink has a tendency to smudge when exposed to humid environments (p. 7). The ink remains chemically stable but is susceptible to physical abrasion if the binder fails or the environment becomes moist.

Scientific Analysis
Chemical CompositionC
Analytical Techniques
X-ray diffraction
preliminary chemical test
Certainty Level
Confirmed
Instrumentally Verified
Verified
Metadata
Material Type
ink
Paper Typecotton rags
ColorBlack
RegionEgypt
Approx. Year1550
Source Information
AuthorHassan, R. R. A., Ali, M. F., Fahmy, A. A., Ali, H. M., & Salem, M. Z.
Collectionlibrary of Al-Azhar Al-Sharif
Language
N/A
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