iron-polyphenol complex
Andalusia
13th Century
Source: Díaz Hidalgo, R. J., et al. (2023). The making of black inks in an Arabic treatise by al-Qalalūsī dated from the 13th c.: reproduction and characterisation of iron-gall ink recipes. Heritage Science, 11(7).
Recipe Details
Ingredients
gallnuts, water, qalqant (crushed vitriol), gum arabic
Preparation Steps
Take the desired quantity of gallnuts and grind them as fine as the powder of antimony. Pour water over it and grind vigorously in a mortar until it forms a foam; then filter the mixture in a thick piece of cloth into another container and add enough crushed qalqant to it: you will see that the mixture will turn black. Then add some gum arabic and write instantly. (p. 8). Reproduction: 3.5 g of galls ground fine, added to 50 mL water, beaten until foam, filtered, 3.5 g of iron sulfate added, and then gum arabic (3.5 g in 17.5 mL). (p. 12).
Original Recipe Text
Take the desired quantity of gallnuts and grind them as fine as the powder of antimony. Pour water over it and grind vigorously in a mortar until it forms a foam; then filter the mixture in a thick piece of cloth into another container and add enough crushed qalqant to it: you will see that the mixture will turn black. Then add some gum arabic and write instantly. (p. 8). Reproduction: 3.5 g of galls ground fine, added to 50 mL water, beaten until foam, filtered, 3.5 g of iron sulfate added, and then gum arabic (3.5 g in 17.5 mL). (p. 12).
Evidence
"QI.11. Instantaneous midād by al-Rāzī: Take the desired quantity of gallnuts and grind them as fine as the powder of antimony. Pour water over it and grind vigorously in a mortar until it forms a foam; then filter the mixture in a thick piece of cloth into another container and add enough crushed qalqant to it"
Remarks
Unique as it does not require boiling or long infusion, relying on the high surface area of fine powder and mechanical agitation (foaming). (p. 4, 8).
Scientific Analysis
Chemical CompositionFe3+-polygalloyl esters of glucose
Analytical Techniques
Raman microscopy
HPLC–DAD
FTIR
Certainty Level
Confirmed
Instrumentally Verified
Verified
Metadata
Material Type
ink
BinderAcacia gum
ColorBlack
RegionAndalusia
Approx. Year1250
Source Information
AuthorDíaz Hidalgo, R. J., et al.
CollectionRecipe by al-Rāzī in al-Qalalūsī treatise
Language
N/A
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