iron-polyphenol complex
Andalusia
13th Century
Source: Díaz Hidalgo, R. J., et al. (2023). The making of black inks in an Arabic treatise by al-Qalalūsī dated from the 13th c.: reproduction and characterisation of iron-gall ink recipes. Heritage Science, 11(7).
Recipe Details
Ingredients
gallnuts, water, vitriol, gum arabic
Preparation Steps
Take thirty gallnuts, grind them, pour three raṭl [1191.78 mL] of water over them and cook on low heat until half is evaporated; then clarify and add five dirham [15.45 g] of weight of good vitriol and seven dirham [21.63 g] of gum arabic; put it in the sun for a couple of days and then write with it. (p. 8). Reproduction variations QI.4Vs1 and QI.4Vs2 tested 100 °C and 70 °C variants to analyze thermal extraction effects. (p. 5, 12).
Original Recipe Text
Take thirty gallnuts, grind them, pour three raṭl [1191.78 mL] of water over them and cook on low heat until half is evaporated; then clarify and add five dirham [15.45 g] of weight of good vitriol and seven dirham [21.63 g] of gum arabic; put it in the sun for a couple of days and then write with it. (p. 8). Reproduction variations QI.4Vs1 and QI.4Vs2 tested 100 °C and 70 °C variants to analyze thermal extraction effects. (p. 5, 12).
Evidence
"QI.4. Another midād by al-Rāzī: Take thirty gallnuts, grind them, pour three raṭl [1191.78 mL] of water over them and cook on low heat until half is evaporated; then clarify and add five dirham [15.45 g] of weight of good vitriol and seven dirham [21.63 g] of gum arabic"
Remarks
Instructions note: 'If it is not black enough and tends to red, add to it some vitriol, while if it is not bright enough, add some gum.' This emphasizes establishing color according to desired 'grade of black and brilliance'. (p. 8).
Scientific Analysis
Chemical CompositionFe3+-polygalloyl esters of glucose
Analytical Techniques
Raman microscopy
HPLC–DAD
FTIR
Certainty Level
Confirmed
Instrumentally Verified
Verified
Metadata
Material Type
ink
BinderAcacia gum
ColorBlack
RegionAndalusia
Approx. Year1250
Source Information
AuthorDíaz Hidalgo, R. J., et al.
CollectionTuḥaf al-ḫawāṣṣ fī ṭuraf al-ḫawāṣṣ, recipe by al-Rāzī
Language
N/A
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