Vermilion, Red lead, Hematite, Orpiment
Iran
9th Century
Source: Holakooei, P., de Lapérouse, J. F., Rugiadi, M., & Carò, F. (2018). Early Islamic pigments at Nishapur, north-eastern Iran: studies on the painted fragments preserved at The Metropolitan Museum of Art. Archaeological and Anthropological Sciences, 10(1), 175-195.
Recipe Details
Ingredients
mercury, sulfur, orpiment, metallic lead, iron oxide
Preparation Steps
Two 10th-11th century recipes (Razi's Ketab al-Asrar and Biruni's al-Saydaneh) describe artificial vermilion manufacture by mixing equal parts mercury and sulfur in a sealed glass jar with a narrow neck and heating in a special kiln (p. 189). Yellow orpiment was often present as an impurity or intentional additive in the manufactured vermilion (p. 189). Red lead was traditionally made in Persia by heating metallic lead sheets in air to transform them into various oxides (litharge, massicot, and red lead) (p. 190).
Original Recipe Text
Two 10th-11th century recipes (Razi's Ketab al-Asrar and Biruni's al-Saydaneh) describe artificial vermilion manufacture by mixing equal parts mercury and sulfur in a sealed glass jar with a narrow neck and heating in a special kiln (p. 189). Yellow orpiment was often present as an impurity or intentional additive in the manufactured vermilion (p. 189). Red lead was traditionally made in Persia by heating metallic lead sheets in air to transform them into various oxides (litharge, massicot, and red lead) (p. 190).
Evidence
"The red pigments which were highly correlated to Hg and S (the paints with a negative value of PC1) are most certainly vermilion (HgS) (p. 178/179)."
Remarks
The presence of orpiment in the vermilion at Nishapur is indicative of artificial manufacture (p. 175). Pink paints were identified as discoloration products of vermilion (p. 179). Hematite has a long history of use in Iran from the Neolithic to medieval times (p. 190).
Scientific Analysis
Chemical CompositionHgS; Pb3O4; Fe2O3; As2S3
Analytical Techniques
XRF
Raman
XRD
optical reflectance spectroscopy
scanning electron microscopy (SEM)
Certainty Level
Confirmed
Instrumentally Verified
Verified
Metadata
Material Type
pigment
ColorPink
RegionIran
Approx. Year850
Source Information
AuthorHolakooei, P., de Lapérouse, J. F., Rugiadi, M., & Carò, F.
CollectionNishapur; Pivezhan area; local manufacture
Language
N/A
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