vermilion

Iran
9th Century
Source: Holakooei, P., de Lapérouse, J.F., Rugiadi, M. & Carò, F. (2018). Early Islamic pigments at Nishapur, north-eastern Iran: studies on the painted fragments preserved at The Metropolitan Museum of Art. Archaeol Anthropol Sci 10:175–195.
Recipe Details

Ingredients

mercury, sulfur

Preparation Steps

The text discusses two historical recipes for artificial vermilion dating back to the tenth and eleventh centuries (Razi and Biruni). The key concept involves mixing fairly equal proportions of mercury and sulfur in a sealed glass jar with a narrow neck and a small hole on top. This procedure involves grinding sulfur with mercury, introducing the ground and blackened product into the jar, and slightly heating it in a special kiln (p. 189). For the application to the wall, soaked calcined calcite—or slaked lime—was mixed and heated with the pigment in a big pan before use as a paint layer (p. 182).

Original Recipe Text

The text discusses two historical recipes for artificial vermilion dating back to the tenth and eleventh centuries (Razi and Biruni). The key concept involves mixing fairly equal proportions of mercury and sulfur in a sealed glass jar with a narrow neck and a small hole on top. This procedure involves grinding sulfur with mercury, introducing the ground and blackened product into the jar, and slightly heating it in a special kiln (p. 189). For the application to the wall, soaked calcined calcite—or slaked lime—was mixed and heated with the pigment in a big pan before use as a paint layer (p. 182).

Evidence

"The red pigments which were highly correlated to Hg and S (the paints with a negative value of PC1) are most certainly vermilion (HgS)."

Remarks

The presence of orpiment as an impurity in the vermilion at Nishapur suggests it was artificially manufactured rather than sourced from natural cinnabar deposits, such as those in the Takab geothermal field, which typically contain barite (absent in Nishapur samples) (p. 189). Pigment use during the 9th-11th centuries in Nishapur is described as being in a trial-and-error stage (p. 175).

Scientific Analysis
Chemical CompositionHgS
Analytical Techniques
XRF
Raman
XRD
optical reflectance spectroscopy
scanning electron microscopy (SEM)
Certainty Level
Confirmed
Instrumentally Verified
Verified
Metadata
Material Type
pigment
Binderslaked lime
ColorRed
RegionIran
Approx. Year850
Source Information
AuthorHolakooei, P., de Lapérouse, J.F., Rugiadi, M. & Carò, F.
CollectionNishapur
Language
N/A
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