brazilwood lake pigments

Spain
13th Century
Source: Vieira, M.; Melo, M.J.; Nabais, P.; Lopes, J.A.; Lopes, G.V.; Fernández, L.F. The Colors in Medieval Illuminations through the Magnificent Scriptorium of Alfonso X, the Learned. Heritage 2024, 7, 272–300.
Recipe Details

Ingredients

brazilwood (Biancaea sappan), alum, lead white, calcium carbonate

Preparation Steps

The process of preparing a lake pigment involves extracting the dye brazilein from the rasps of the wood with an alkaline or neutral solution and complexing it with a metallic ion, usually by adding alum (p. 274). In the Rich codex and Book of Games, it was applied as a thin varnish-like layer (p. 286). In the Musicians’ codex and Lapidary, it was often mixed with lead white and fillers like gypsum or calcium carbonate to improve opacity and mechanical performance (p. 286).

Original Recipe Text

The process of preparing a lake pigment involves extracting the dye brazilein from the rasps of the wood with an alkaline or neutral solution and complexing it with a metallic ion, usually by adding alum (p. 274). In the Rich codex and Book of Games, it was applied as a thin varnish-like layer (p. 286). In the Musicians’ codex and Lapidary, it was often mixed with lead white and fillers like gypsum or calcium carbonate to improve opacity and mechanical performance (p. 286).

Evidence

"The pinks and purples identified in all the manuscripts have a colorant in common: brazilwood lake pigment. It was identified through its absorbance spectra, with a maximum of around 555 nm."

Remarks

This represents the first reported use of brazilwood lake pigment in European medieval manuscript illumination (Abstract). In the Rich codex, pure colors were preferred to create light/dark contrasts by controlling paint thickness on the parchment (p. 279). In contrast, the other codices utilize thick-layer paints with extensive mixtures and additives (p. 280).

Scientific Analysis
Chemical Compositionbrazilein complexed with Al3+
Analytical Techniques
Raman
fiber-optics reflectance spectroscopy (FORS)
Certainty Level
Confirmed
Instrumentally Verified
Verified
Metadata
Material Type
pigment
Bindertempera (proteinaceous or polysaccharide)
Paper TypeParchment
ColorPurple
RegionSpain
Approx. Year1250
Source Information
AuthorVieira, M.; Melo, M.J.; Nabais, P.; Lopes, J.A.; Lopes, G.V.; Fernández, L.F. The Colors in Medieval Illuminations through the Magnificent Scriptorium of Alfonso X, the Learned. Heritage 2024, 7, 272–300.
CollectionRich codex (T-I-1), Musicians’ codex (b-I-2), Lapidary (h-I-15), Book of Games (T-I-6)
Language
N/A
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