Wood pulp paper
Italy
20th Century
Source: Chiriu, D., Ricci, P. C., Cappellini, G., Salis, M., Loddo, G., & Carbonaro, C. M. (2018). Ageing of ancient paper: A kinetic model of cellulose degradation from Raman spectra. Journal of Raman Spectroscopy, 49(11), 1802-1811.
Recipe Details
Ingredients
cellulose, wood pulp, lignin
Preparation Steps
The sample is identified as wood pulp paper due to the high lignin content (p. 1804). Lignin is mainly responsible for degradation in modern papers (since the XIX century) due to its photo-oxidation properties (p. 1804). The study uses Equation 1 to estimate the 'effective age' by measuring the ratio of residual unbroken glycosidic bonds (p. 1806).
Original Recipe Text
The sample is identified as wood pulp paper due to the high lignin content (p. 1804). Lignin is mainly responsible for degradation in modern papers (since the XIX century) due to its photo-oxidation properties (p. 1804). The study uses Equation 1 to estimate the 'effective age' by measuring the ratio of residual unbroken glycosidic bonds (p. 1806).
Evidence
"The fingerprint showing the presence of lignin in the paper composition is the vibrational band centred at 1,602 cm−1... The worst conservation status was recorded for the C2E sample, whose printing date claims for less than 100 years of ageing whilst the estimated effective date is more than 300 years for the whitest point."
Remarks
The C2E sample (Radioactivité, 1935) showed extreme degradation despite its relatively recent chronological date. The Raman-estimated age exceeded 300–400 years (p. 1809), which authors attribute to the presence of lignin and non-optimal conservation conditions including public handling and environmental factors (p. 1809).
Scientific Analysis
Chemical Composition(C6H10O5)n and Lignin
Analytical Techniques
Raman
Certainty Level
Confirmed
Instrumentally Verified
Verified
Metadata
Material Type
paper
Paper TypeWood pulp paper
RegionItaly
Approx. Year1950
Source Information
AuthorChiriu, D., Ricci, P. C., Cappellini, G., Salis, M., Loddo, G., & Carbonaro, C. M.
CollectionDepartment of Physics—University of Cagliari
Language
N/A
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