indigo, Prussian blue, red lead, carbon-based black, lead white, lazurite, orpiment, malachite, vermilion, gold
Iran
18th Century
Source: Burgio, L., Clark, R. J. H., Muralha, V. S. F., & Stanley, T. (2008). Pigment analysis by Raman microscopy of the non-figurative illumination in 16th- to 18th-century Islamic manuscripts. Journal of Raman Spectroscopy, 39(10), 1482-1493.
Recipe Details
Ingredients
indigo, Prussian blue, red lead, carbon-based black, lead white, lazurite, orpiment, malachite, vermilion, gold
Preparation Steps
Indigo used for the dark blue grounds of the 18th-century frames (p. 1492). Prussian blue, a synthetic pigment introduced in the early 18th century, used for blue frames (p. 1492). Red lead for orange pigments; carbon-based black and lead white for black and white frames (p. 1492). Diacritics on original 11th-century leaves contain vermilion, lazurite, orpiment, and malachite (p. 1492). Gold leaf/paint used for ruled frames and floral scroll patterns (p. 1485).
Original Recipe Text
Indigo used for the dark blue grounds of the 18th-century frames (p. 1492). Prussian blue, a synthetic pigment introduced in the early 18th century, used for blue frames (p. 1492). Red lead for orange pigments; carbon-based black and lead white for black and white frames (p. 1492). Diacritics on original 11th-century leaves contain vermilion, lazurite, orpiment, and malachite (p. 1492). Gold leaf/paint used for ruled frames and floral scroll patterns (p. 1485).
Evidence
"The dark blue ground had the typical appearance of indigo, and its characteristic bands at 1584, 1575, 599, and 546 cm1 were detected. (p. 1492) ... The material employed for the blue of the frame is Prussian blue (Fe4[Fe(CN)6]3 . 14–16 H2O)... its Raman spectrum shows characteristic bands at 2154, 2102, 538, and 282 cm1. (p. 1492)"
Remarks
This album contains 11th-century Qur'an leaves set into 18th-century paper frames (p. 1485). Prussian blue is noted as the earliest known modern synthetic pigment, introduced to Iran in the mid-18th century (p. 1492). 11th-century diacritics were color-coded (red vowels, green hamzat al-qat', blue shaddah, yellow alternative readings) (p. 1485).
Scientific Analysis
Chemical CompositionC16H10N2O2, Fe4[Fe(CN)6]3, Pb3O4, 2PbCO3·Pb(OH)2, (Na,Ca)8[Al,Si12O24]Sn, As2S3, Cu2CO3(OH)2, HgS, Au
Analytical Techniques
XRF
Raman microscopy (RM)
Certainty Level
Confirmed
Instrumentally Verified
Verified
Metadata
Material Type
pigment
Paper TypeParchment
ColorYellow
RegionIran
Approx. Year1750
Source Information
AuthorBurgio, L., Clark, R. J. H., Muralha, V. S. F., & Stanley, T.
CollectionVictoria and Albert Museum, MSL/1876/689
Language
N/A
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