silver (metallurgical dyeing)

Byzantium
14th Century
Source: Martelli, M. (2023). Late Byzantine Alchemical Recipe Books: Metallurgy, Pharmacology, and Cuisine. In Baki, C. & Eneyni, R. (Eds.), Policy Advisory Systems in Autocracies (pp. 336-353). Cambridge University Press.
Recipe Details

Ingredients

mercury, unburnt sulphur, lead, Alexandrian vitriol

Preparation Steps

To produce a silver-colored material: Combine equal parts mercury and unburnt sulphur in a crucible. Heat over a gentle fire (comparable to the sun's warmth) while stirring frequently. Once the mixture solidifies and dries, purify the resulting mass with lead to achieve a 'shining silver' appearance. If the material is too hard, Alexandrian vitriol may be added to the crucible for softening (p. 349).

Original Recipe Text

To produce a silver-colored material: Combine equal parts mercury and unburnt sulphur in a crucible. Heat over a gentle fire (comparable to the sun's warmth) while stirring frequently. Once the mixture solidifies and dries, purify the resulting mass with lead to achieve a 'shining silver' appearance. If the material is too hard, Alexandrian vitriol may be added to the crucible for softening (p. 349).

Evidence

"In order to make silver. Take as much mercury as you want and unburnt sulphur, the same quantity, put them in a vessel, [i.e.] a crucible, and set on a gentle fire as warm as the heat of the sun and stir it often; after reaching the solidification of the mixture and letting it get dry, purify it with lead and it will become shining silver. If it is hard and you want to soften it, throw Alexandrian vitriol in the crucible."

Remarks

This is a metallurgical dyeing procedure for creating an alloy or surface treatment resembling silver. It reflects a technique for making 'artificial cinnabar' popular in Byzantium (p. 350).

Scientific Analysis
Chemical CompositionHg, S, Pb, CuSO4 or FeSO4
Analytical Techniques
philological analysis
Certainty Level
Inferred
Instrumentally Verified
Not Verified
Metadata
Material Type
pigment
ColorSilver
RegionByzantium
Approx. Year1350
Source Information
AuthorMartelli, M.
CollectionMS Vaticanus gr. 1174, f. 49v
Language
N/A
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